Journal
SYNLETT
Volume -, Issue 19, Pages 2749-2752Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1316555
Keywords
palladium; C-H activation; alkenes; acetonitrile; pyridine
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Funding
- National Basic Research Program of China [973-2009CB825300]
- National Natural Science Foundation of China [20972175, 20923005, 21121062]
- Chinese Academy of Science
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A palladium-catalyzed oxidative arylalkylation of unactivated alkenes involving dual C-H bond cleavage of arene and acetonitrile was developed. This reaction was promoted by pyridine as a ligand, and the ratio of palladium to pyridine is vital for this transformation. A series of nitrile-containing indolines were efficiently provided in moderate to good yields.
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