Journal
SYNLETT
Volume -, Issue 11, Pages 1621-1624Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1291163
Keywords
quinone; aryl diazonium salt; aniline; direct C-H arylation; radical
Categories
Funding
- 'Ligue Contre Le Cancer', the 'Agence Nationale de la Recherche' [ANR JCJC 7141]
- Association pour la Recherche sur le Cancer (ARC)
- Region Aquitaine
- Centre National de Recherche Scientifique (CNRS)
Ask authors/readers for more resources
We discovered that anilines were suitable for the direct C-H arylation of benzoquinone in the presence of tert-butyl nitrite. This new reaction proceeds through the in situ formation of a diazonium hydroxide species. The coupling can be carried out at room temperature under neutral, additive-free, metal-free, and aqueous conditions, allowing an environmentally friendly procedure.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
