Journal
SYNLETT
Volume -, Issue 10, Pages 1345-1356Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260572
Keywords
asymmetric catalysis; diene complexes; Michael additions; cross-coupling; rhodium
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Funding
- National Natural Science Foundation of China [21002112]
- Major State Basic Research Development Program [2010CB833302]
- Shanghai Municipal Committee of Science and Technology [09JC1417300]
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This account summarizes our efforts on the design, synthesis, and application of two classes of chiral diene ligands bearing bicyclo[3.3.0] octadiene or dicyclopentadiene skeletons. These chiral diene ligands can be readily prepared from inexpensive commercial materials with enzymatic resolution as the key synthetic step. The ligands have been successfully applied in some rhodium-catalyzed reactions, including 1,4-addition to alpha, beta-unsaturated carbonyl compounds, arylation of imines, and conjugate addition to nitroalkenes. In addition, they have been used in the first successful palladium-diene-catalyzed asymmetric reaction.
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