Journal
SYNLETT
Volume -, Issue 4, Pages 547-550Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1259514
Keywords
total synthesis; 7-isocyanoamphilecta-11(20); 15-diene; isocyanide; intramolecular Diels-Alder reaction; intramolecular Michael reaction
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The total synthesis of amphilectane-type diterpenoid (+/-)-7- isocyanoamphilecta-11(20),15-diene, isolated from the tropical marine sponge Cymbastela hooperi, was achieved. The synthesis involves construction of a cis-decalin ring by an intramolecular Diels-Alder reaction and construction of an all-trans-perhydrophenalene ring by an intramolecular Michael reaction as the key steps.
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