Journal
SYNLETT
Volume -, Issue 4, Pages 579-581Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1259519
Keywords
bisfunctionalization reactions; olefins; palladium-catalyzed reactions; selective
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Funding
- Natural Scientific Foundation of Jiangsu Province [BK2010321]
- University Natural Scientific Foundation of Jiangsu Province [09KJB150014]
- 45th Postdoctor foundation of China [20090451249]
- National Natural Scientific Foundation of China [20633010, 20773106]
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The palladium-catalyzed reaction of olefins with PhI(OAc)(2)-TBAB system provides a novel, efficient, and highly selective bisfunctionalization strategy to introduce bromo and oxygen groups simultaneously. The substituents on the C=C bond control the regioselectivity of this reaction, which could be an effective supplement of bromohydroxylation in organic synthesis.
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