Journal
SYNLETT
Volume -, Issue 4, Pages 569-572Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1259520
Keywords
homocoupling; oxidative dehydrogenation; copper catalyst; direct synthesis; hydrazine
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Funding
- National Natural Science Foundation of China [20872059, 21072091]
- MOST of China [2011CB808600]
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A copper-catalyzed N-N bond-forming reaction was performed by a dehydrogenative homocoupling of N-alkylanilines, affording N, N'-dialkyl-N, N'-diphenylhydrazines in 72-88% yields. This new strategy has the advantages of direct synthesis from N-alkylanilines, using air as the oxidant, convenient manipulations, mild reaction conditions and moderate to good yields. A possible mechanism by coordination and reductive elimination has been proposed.
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