Journal
SYNLETT
Volume -, Issue 5, Pages 659-662Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1259690
Keywords
polymer-supported organocatalyst; polystyrene; DMAP; carbon dioxide; cyclic carbonate
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Funding
- University of Hong Kong
- Research Grants Council of the Hong Kong S. A. R, P. R. of China [HKU 704108P]
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Rasta resin-DMAP, a new heterogeneous polystyrene-based amine, has been synthesized and used as a catalyst in addition reactions of carbon dioxide to epoxides to afford cyclic carbonate products. This new material was found to be a more efficient catalyst than divinyl benzene cross-linked polystyrene-supported DMAP, and was readily recovered and reused without significant loss of catalytic activity.
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