Journal
SYNLETT
Volume -, Issue 8, Pages 1247-1250Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1219787
Keywords
resveratrol dimmer; pallidol; ampelosin F; oxidative coupling; biosynthesis
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Funding
- Lanzhou Jiaotong University
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A wide array of natural resveratrol dimers was prepared by the regioselective oxidative coupling reaction of 3,5-di-(tert-butyl) resveratrol using several types of metal oxidants (Ag(2)O, Ag(2)CO(3), MnO(2), and FeCl(3)center dot 6H(2)O) in different solvent systems (benzene-acetone and dichloromethane). Subsequent debutylation of these coupling products resulted in racemic pallidol and ampelosin F.
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