Journal
SYNLETT
Volume -, Issue 3, Pages 383-386Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1219174
Keywords
oxidative deamination; alpha-ketophosphonates; alpha-hydroxyphosphonates; amines; aldehydes
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Funding
- Birjand University Research Council
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A novel method for the rapid and efficient conversion of a variety of alpha-aminophosphonates to alpha-ketophosphonates using ZnCr2O7 center dot 3H(2)O via oxidative deamination under solvent-free conditions at room temperature is described. This method is also applicable to the rapid and highly selective oxidation of various types of ordinary amines (primary and secondary) to aldehydes and ketones in good to high yields.
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