4.4 Article

Rediscovering Organocopper Chemistry Through Copper Hydride. It's All About the Ligand

Journal

SYNLETT
Volume -, Issue 4, Pages 509-524

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0028-1087923

Keywords

ligands; asymmetric catalysis; copper hydride; hydro-silylations; asymmetric catalysis

Funding

  1. NSF

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A personalized account is presented that reveals the real stories behind the development of copper hydride chemistry at UCSB over the past decade: names, events, and the thinking behind the discoveries. Both achirally ligated and nonracemically complexed copper hydride reagents are discussed within the context of the field as a whole.

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