Journal
SYNLETT
Volume -, Issue 12, Pages 1985-1989Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1217543
Keywords
catalysis; indoles; allenes; dienes; nucleophilic substitution
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Funding
- Junta de Castilla y Leon [BU012A06]
- Ministerio de Educacion y Ciencia (MEC)
- FEDER [CTQ2007-61436/BQU]
- Young Foreign Researchers [SB2006-0215]
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The Bronsted acid catalyzed direct nucleophilic substitution of tertiary propargylic alcohols with 2-aryl-substituted indoles has been studied. A competitive allenylation process takes place with appropriate substituents on the alkynol moiety. Starting from 2-arylindoles, new 3-allenyl and 3-dienylindole derivatives have been easily synthesized.
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