4.4 Article

A Novel Approach to Stilbenoid Dendrimer Core Synthesis

Journal

SYNLETT
Volume -, Issue 19, Pages 3026-3030

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0028-1083630

Keywords

cross-coupling; palladium catalyst; stilbenoid dendrimer cores; silicon derivatives

Funding

  1. Ministry of Science and Higher Education (Poland) [NN 204 238734, 204 162 32/4248]

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A new synthetic protocol for the one-pot, stereoselective synthesis of 1,3,5-tris[(E)-4-halostyryl]benzene and 1,2,4,5-tetrakis[(E)-4-halostyryl] benzene derivatives as stilbenoid dendrimer cores via palladium-catalyzed Hiyama cross-coupling of aryl tri- or tetrahalides with 1,3-bis[(E)-4-halostyryl]disiloxanes is described.

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