Journal
SYNLETT
Volume -, Issue 19, Pages 2938-2940Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0028-1087354
Keywords
phosphine oxides; nucleophilic aromatic substitution; nitroarenes; carbanions
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Potassium and sodium salts of diphenylphosphine add to nitroarenes in the position ortho and para to the nitro group. Subsequent oxidation of sigma(H)-adducts with potassium permanganate gave diphenyl(nitroaryl)phosphine oxides.
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