Journal
SYNLETT
Volume -, Issue 12, Pages 1809-1812Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1078525
Keywords
cross-coupling; halides; ligands; palladium
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A new ligand, diphenylmethylcyclopropylphosphine, has successfully been applied in the palladium-catalyzed Suzuki-Miyaura coupling and alpha-arylation of ketones with aryl chlorides in moderate to high yields. An asymmetric coupling between anisyl chloride and 2-methylindan-1-one was also tested as the first trial, giving 80% yield and 41% ee with 1 mol% of Pd.
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