Journal
SYNLETT
Volume -, Issue 12, Pages 1801-1804Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1078504
Keywords
curvularin; cytotoxic; ring-closing metathesis; Pinnick oxidation; Wittig reaction
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A convergent, flexible, and efficient approach to the synthesis of curvularin is described. Key step is the high-yielding macrocyclic ring formation by ring-closing metathesis (RCM) using the Grubbs second-generation catalyst.
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