Journal
SYNLETT
Volume -, Issue 11, Pages 1669-1672Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1078492
Keywords
oxime ether; (+)-nopinone; stereocontrolled alkylation; amino alcohols
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Funding
- French Ministry of Industry
- CIFRE
- CNRS
- French Ministry of Research
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The alkylation of (+)-nopinone oxime ether with various electrophiles afforded the corresponding adduct with a total stereoselectivity. Further reduction of the oxime ether afforded an easily access to new chiral gamma-and delta-amino alcohols of high interest for catalysis and asymmetric synthesis.
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