Journal
SYNLETT
Volume -, Issue 12, Pages 1813-1816Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1078570
Keywords
heterogeneous catalysis; ionic liquids; methathesis; ruthenium; supported catalysis
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Grubbs olefin metathesis catalyst was immobilized as a ruthenium-supported ionic liquid catalyst (Ru-SILC) in pores of amorphous alumina with the aid of ionic liquid [hmim]PF6. This Ru-SILC was effective for various olefin metathesis reactions such as intra- or intermolecular macrocyclization and dimerization, and used up to six times after simple decantation.
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