4.4 Article

Dynamics of small mobile helium clusters near tungsten surfaces

Journal

SURFACE SCIENCE
Volume 626, Issue -, Pages 21-25

Publisher

ELSEVIER
DOI: 10.1016/j.susc.2014.03.020

Keywords

Plasma-exposed tungsten; Mobile helium clusters; Surface segregation; Diffusion; Surface structure and morphology; Molecular dynamics simulations

Funding

  1. U.S. Department of Energy, Office of Fusion Energy Sciences and Office of Advanced Scientific Computing Research through the Scientific Discovery through Advanced Computing (SciDAC) project on Plasma-Surface Interactions [DE-SC0008875]
  2. U.S. Department of Energy, Office of Fusion Energy Sciences through the Plasma-Surface Interactions Science Center [DE-SC0002060]
  3. U.S. Department of Energy (DOE) [DE-SC0002060] Funding Source: U.S. Department of Energy (DOE)

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We report the results of a systematic atomic-scale analysis of the dynamics of small mobile helium clusters in tungsten, near tungsten surfaces. These helium clusters are attracted to tungsten surfaces due to an elastic interaction force that drives surface segregation. As the clusters migrate toward the surface, trap mutation and cluster dissociation are activated at rates higher than in the bulk. These kinetic processes are responsible for important structural, morphological, and compositional features in plasma-exposed tungsten, including surface adatoms, near-surface immobile helium-vacancy complexes, and retained helium content. Detailed results are presented for di-helium and tri-helium clusters near low-Miller-index tungsten surfaces. (C) 2014 Elsevier B.V. All rights reserved.

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