Journal
SURFACE SCIENCE
Volume 604, Issue 13-14, Pages 1065-1069Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.susc.2010.03.004
Keywords
Iron oxyhydroxide; Nuclear magnetic resonance; X-ray absorption spectroscopy; X-ray scattering; Diffraction; Infrared spectroscopy
Categories
Funding
- National Science Foundation (NSF) [1065905]
- FeOOH CRC
- Division Of Mathematical Sciences
- Direct For Mathematical & Physical Scien [1065905] Funding Source: National Science Foundation
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In this prospective, new developments in the study of the structure and reactivity of iron oxyhydroxides are reviewed. These materials are of particular interest, since their surfaces control an extraordinary amount of environmental chemistry. Understanding the environmental interfaces at a molecular level often appears to be a daunting scientific endeavor at first glance. Surfaces of interest range from the nano to micron regime and appear in the environment in varying shapes and sizes. Often the powerful suite of vacuum-based surface science tools are not applicable, since the surfaces of environmental particles can vary from amorphous to semi-crystalline and their surface reactivity is often affected by varying levels of surface hydration. However, the introduction of new and powerful surface probes and advancements in computational chemistry are allowing surface scientists to shed light on these hidden interfaces and how they control environmental chemistry. (C) 2010 Elsevier B.V. All rights reserved.
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