Journal
SURFACE AND INTERFACE ANALYSIS
Volume 45, Issue 8, Pages 1206-1210Publisher
WILEY
DOI: 10.1002/sia.5253
Keywords
Nb film; X-ray photoelectron spectroscopy; ultraviolet photoelectron spectroscopy; density of state
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Funding
- Science and Technology Foundation of State Key Laboratory [9140c6806080c68]
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In this paper, the electronic structures of NbO2 and Nb2O5 are theoretically and experimentally analyzed. The oxides in the samples are mainly consisted of NbO2 and NbO, whereas the outmost layer of the samples is NbO2. After exposure to air, the outermost layer on all niobium samples is Nb2O5. The photoelectrons from the first 2-4 angstrom contribute to the spectra, so the valence band structure of NbO2 and Nb2O5 can be confirmed from ultraviolet photoelectron spectroscopy (UPS). By comparing the UPS with density of state results, the electronic structure of NbO2 and Nb2O5 can be distinguished from each other, and then the electronic structure was deconvoluted into several electronic states. The agreement between experimental result and theory is, in the best case, satisfactory. Copyright (c) 2013 John Wiley & Sons, Ltd.
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