Plasma modification of polylactic acid in a medium pressure DBD

In this paper, a dielectric barrier discharge (DBD) operating in different atmospheres (air, nitrogen, helium and argon) and at medium pressure is employed to modify the surface properties of polylactic acid (PLA). Chemical and physical changes on the plasma-treated surfaces are examined using contact angle. X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) measurements. Results show that the discharge gas can have a significant influence on the chemical composition of the PLA surfaces: air and argon plasmas introduce oxygen-containing groups, while nitrogen discharges add nitrogen groups to the PLA surface. Quite surprisingly, also helium plasmas incorporate a small amount of nitrogen-containing functionalities: this observation can however be explained by the fact that the helium discharge operates in the glow mode. In the near future, it will be examined whether the performed plasma treatments can enhance PLA cell attachment and proliferation, which might open the door to many interesting biomedical applications. (C) 2010 Elsevier B.V. All rights reserved.