Journal
SUPRAMOLECULAR CHEMISTRY
Volume 27, Issue 5-6, Pages 401-406Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2014.975703
Keywords
single-ion magnet; magnetic relaxation; single-molecular magnet; supramolecular polymer
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Funding
- National Natural Science Foundation of China [21104015, 21172050, 21302035, 21371043]
- Thousand Young Talents Program of China
- Fundamental Research Funds for the Central Universities
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Natural Science Foundation of Jiangsu Province of China [BK2011778]
- Beijing National Laboratory for Molecular Sciences (BNLMS)
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We have investigated the dynamic behaviour of the magnetization of a hydrogen-bonding linked Co(II) 1D supramolecular coordination polymer. In the structure, two different mononuclear Co(II) species are linked by O-H center dot center dot center dot N hydrogen bonding through coordinated H2O and [GRAPHICS] . Field-induced slow magnetic relaxation effect is observed and the anisotropy energy barrier is 33K. Ab initio calculations reveal that Co(II) ion in [Co(bpm)(2)(N-3)(2)] species is uniaxial anisotropic with a negative axial zero-field splitting parameter of D=-82.4cm(-1). The Co(II) ion in [Co(bpm)(2)(H2O)(2)](2+) species, however, is easy-plane anisotropic with a positive D and negative E value (D=46.3cm(-1), E=-7.8cm(-1)). This is an interesting complex in which slow magnetic relaxation stems from the combination contribution of uniaxial anisotropy and easy plane anisotropy.
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