Journal
SUPRAMOLECULAR CHEMISTRY
Volume 25, Issue 9-11, Pages 672-681Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2013.822975
Keywords
host-guest chemistry; molecular recognition; phosphonate cavitand; acetylcholine; fluorescence
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Experimental approaches to tetraphosphonate cavitands bearing fluorenyl-phosphonate bridges are reported. Different routes are described depending on the substitution on the cavitand structure. Tetra-, tri- and di-bridged phosphonate cavitands have been prepared as precursors of fluorescent hosts, for which the stereochemistry is highly dependent on the substitution at the wide rim of the resorcin[4]arene scaffold. The conformational change in 3io tetraphosphonate cavitands has been characterised by X-ray diffraction. These new molecular receptors have been used for the recognition of acetylcholine.
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