Journal
SUPRAMOLECULAR CHEMISTRY
Volume 23, Issue 11, Pages 721-730Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2011.622390
Keywords
thiosemicarbazides; columnar liquid crystals; mesomorphism
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Funding
- FONDECYT [1100140]
- CONICYT
- FULLBRIGHT
- 'Direccion de Investigacion' of the University of Concepcion
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Novel liquid crystal materials based on 3,4-di-n-alkoxybenzoylthiosemicarbazides (3a-h, n = 5-10, 12, 14) were synthesised. The mesomorphic properties of these compounds were characterised and studied by differential scanning calorimetry, polarising optical microscopy and X-ray diffraction. Compound 3a did not show mesomorphic properties; 3b shows a monotropic hexagonal columnar (Col(h)) phase. Compounds 3c-h display an enantiotropic Col(h) phase. The mesomorphic properties were found to be dependent on the length of alkoxy side chains. In N,N-dimethylformamide solution, all the compounds displayed a room temperature emission with lambda(max) at 361-332 nm. A thermogravimetric analysis also was performed.
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