Journal
SUPRAMOLECULAR CHEMISTRY
Volume 22, Issue 11-12, Pages 710-716Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2010.500729
Keywords
host-guest complexes; cucurbiturils; electrochemistry; non-aqueous solvents
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Funding
- University of Miami
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The redox-active guests (ferrocenylmethyl)trimethylammonium (2+) and methylviologen (52+) form stable complexes with the cucurbit[7]uril host (CB7) in aqueous solution. In this work, we report a method to transfer these cationic inclusion complexes - as their hexafluorophosphate salts - to less polar, non-aqueous solvents, such as CH3CN, dimethylformamide and dimethylsulphoxide (DMSO). Both inclusion complexes were found to be stable in these solvents, although the determination of accurate equilibrium association constants was hampered by the low solubility of the free host. Voltammetric experiments show that the one-electron oxidation of the ferrocenyl residue in the CB7 center dot 2+ complex increases its stability in CH3CN and DMSO solutions, while the opposite effect was observed in aqueous media. These results provide valuable insight into the various roles played by hydrophobic interactions, solvation effects and ion-dipole interactions at stabilising CB7 inclusion complexes of cationic guests.
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