Journal
CHEMPLUSCHEM
Volume 81, Issue 1, Pages 73-79Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201500346
Keywords
electrochemistry; fluorinated ligands; luminescence; photophysics; ruthenium
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Funding
- National Basic Research Program of China (973 Program) [2014CB643505, 2013CB834701]
- National Science Foundation of China [21334002, 91233113]
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Five 3,5-difluorophenyl-substituted ruthenium complexes [Ru(bpy)(2)(dfpbpy)(ClO4)(2)] (Ru-Fbpy-bpy; bpy=bipyridine, dfpbpy=5,5-di(3,5-difluorophenyl)-2,2-bipyridine), [Ru(dpp)(2)(dfpbpy)(ClO4)(2)] (Ru-Fbpy-dpp; dpp=4,7-diphenyl-1,10-phenanthroline), [Ru(dpp)(2)(dfpphen)(ClO4)(2)] (Ru-Fphen-dpp; dfpphen=5,5-di(3,5-difluorophenyl)-1,10-phenanthroline), [Ru(dpp)(2)(4,7-dfpphen)(ClO4)(2)] (Ru-Fdpp-dpp; 4,7-dfpphen=4,7-di(3,5-difluorophenyl)-1,10-phenanthroline), and [Ru(4,7-dfpphen)(3)(AsF6)(2)] (Ru-Fdpp) were synthesized, and their photophysical, electrochemical, and electroluminescent properties were studied systematically. The introduction of the electron-withdrawing group 3,5-difluorophenyl leads to a redshift of the emission of the ruthenium complexes. In addition, the 3,5-difluorophenyl substituent extends the conjugation of the ligand, and thus facilitates the metal-to-ligand charge-transfer process of the complexes. All the complexes display orange-red phosphorescent emissions centered at 638, 638, 624, 614, and 605nm, respectively. Density functional theory calculations show that the lowest unoccupied molecular orbital of Ru-Fbpy-dpp, Ru-Fphen-dpp, and Ru-Fdpp-dpp are all distributed on the 3,5-difluorophenyl-substituted ligand. By using these complexes as emitters, highly luminescent single-layer devices are obtained. The optimized device based on Ru-Fdpp exhibits the highest luminous efficiency and power efficiency of 4.19cdA(-1) and 1.46lmW(-1), respectively.
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