Journal
CHEMPLUSCHEM
Volume 80, Issue 10, Pages 1556-1564Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201500293
Keywords
adsorption; biomass; carbohydrates; epoxidation; mesoporous materials
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Funding
- A*Star, PSF [WBS: R-279-000-403-305]
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The production of a series of mesoporous, nitrogen-containing (N-containing) carbon materials directly from pure chitin by means of carbonization at different temperatures under template-free conditions is reported. Thermogravimetric analysis combined with infrared spectroscopy was applied to follow the temperature-dependent chemical events during the carbonization process, thereby shedding light on the automated pore formation mechanism. The physicochemical properties of the N-containing carbon materials have been extensively investigated, which provided guidance and rational understanding of the application of these materials. It was found that the N-containing carbon materials obtained at lower temperatures (400-600 degrees C) were enriched with amine, amide, and pyrrolic functionalities, which enables their very high efficiency as adsorbents to remove toxic heavy metals, such as Cr-VI, Hg-II, and Pd-II, from water. In contrast, N-containing carbon materials prepared at higher temperatures (800-1000 degrees C) were enriched with graphitic N, which exhibited excellent catalytic activity in the epoxidation of styrene.
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