3D Interlayer Nanohybrids Composed of Sulfamic-Acid-Doped PEdot Grown on Expanded Graphite for High-Performance Supercapacitors

Sulfamic acid (SFA)-doped poly(3,4-ethylenedioxythiophene) (PEdot) grown on expanded graphite (EG) nanohybrids (S-PEdot/EG) were synthesized by surfactant-free insitu chemical oxidative polymerization. The 3D hierarchical structure S-PEdot/EG with homogenous ridgelike surface morphology was achieved by intercalating 3,4-ethylenedioxythiophene monomers between the interlayers of EG using a vacuum-assisted method. The composition of the nanohybrids and the - interaction between the EG and PEdot molecules were characterized by using Raman spectroscopy, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The nanohybrid with an EG content of 10% exhibited excellent capacitive performance with a high capacitance of 139.6Fg(-1) at 1.0Ag(-1) in 1m LiClO4 electrolyte. In the two-electrode symmetric supercapacitors, the device performed with a high energy density of 6.83Whkg(-1) at the power density of 146Wkg(-1), and retained high stability during the charge-discharge process. The excellent performance can be attributed to the 3D hierarchical structure, the - interaction between EG and PEdot molecules, and the doped SFA as an immobilized counter-ion. This cost-effective and simple method used to fabricate 3D S-PEdot/EG nanohybrids is promising for the generation of electrode materials for high-performance supercapacitors.