Elemental analysis of halogens using molecular emission by laser-induced breakdown spectroscopy in air

Fluorine and chlorine do not produce atomic and ionic line spectra of sufficient intensity to permit their detection by laser-induced breakdown spectroscopy. They do, however, combine with alkali-earths and other elements to form molecules whose spectra may be easily identified, enabling detection in ambient conditions with much higher sensitivity than using FI and Cl I atomic lines. (C) 2014 Elsevier B.V. All rights reserved.