Journal
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
Volume 63, Issue 7, Pages 784-792Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.sab.2008.04.012
Keywords
laser-induced plasma spectroscopy; LIBS; curve-of-growth; plasma characterization
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Laser-induced plasmas have been characterized by emission spectroscopy, including the measurement of curves of growth. The plasmas have been generated in air at atmospheric pressure using an infrared Nd:YAG laser from a set of Fe-Ni alloys with varying Fe concentrations. The procedure used provides, in addition to the apparent temperature T and electron density N-e a parameter N'l (the atom number density for 100% concentration times the length of the plasma along the line-of-sight), relevant to obtain the self-absorption and the intensity of the emission lines. The temporal evolution of the plasma parameters has been deduced from the measurement and fitting of the curves of growth. A fast temporal decrease of N'l is obtained for ions, whereas a gradual increase takes place for neutral atoms. The temporal evolution of the line intensity in the optically thin limit and the self-absorption of neutral atom and ion lines have been obtained experimentally and calculated from the evolution of the plasma parameters. The usefulness of the curve-of-growth method in measurements with time integration, in spite of the fast variation of the plasma parameters, has been demonstrated. (C) 2008 Elsevier B.V. All rights reserved.
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