Adsorption behaviour of direct yellow 50 onto cotton fiber: Equilibrium, kinetic and thermodynamic profile

This study investigated the adsorption of direct yellow 50 onto cotton fiber from aqueous solution by using parameters, such as pH, temperature, contact time, initial dye concentration and the effect of sodium sulphate, tetrasodium edate and trisodium citrate. The extent of dye adsorption increased with increasing contact time, temperature and solution concentration. The experimental data were analyzed by the Langmuir and Freundlich models of adsorption. It was found that the Langmuir equation fit better than the Freundlich equation. The results show that the presence of SE and SC significantly enhance the dye adsorption onto cotton fiber. In addition, the adsorption data obtained at different temperatures of DY50 onto cotton fiber were applied to pseudo first-order, pseudo second-order and intraparticle diffusion models. The rates of adsorption were found to conform to pseudo second-order kinetics with good correlation. Also, free energy of adsorption (Delta G(#)), enthalpy (Delta H-#), and entropy (Delta S-#) changes were determined to predict the nature of adsorption. The positive value of the enthalpy change indicated that the adsorption is endothermic process. The activation energy, E-a, is ranged between 1.9 and 3.9 kJ mol(-1) indicated that the adsorption process is a physisorption. This low value of E-a generally indicates diffusion controlled process. (C) 2014 Published by Elsevier B.V.