Journal
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume 99, Issue -, Pages 102-109Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2012.09.025
Keywords
Tea waste; Cationic and anionic dyes; Magnetite; Removal; Kinetic model; Adsorption model
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Adsorption of seven different organic dyes from aqueous solutions onto magnetite nanoparticles loaded tea waste (MNLTW) was studied. MNLTW was prepared via a simple method and was fully characterized. The properties of this magnetic adsorbent were characterized by scanning electron microscopy and X-ray diffraction. Adsorption characteristics of the MNLTW adsorbent was examined using Janus green, methylene blue, thionine, crystal violet, Congo red, neutral red and reactive blue 19 as adsorbates. Dyes adsorption process was thoroughly studied from both kinetic and equilibrium points of view for all adsorbents. The experimental isotherm data were analyzed using Langmuir, Freundlich, Sips, Redlich-Peterson, Brouers-Sotolongo and Temkin isotherms. The results from Langmuir isotherm indicated that the capacity of MNLTW for the adsorption of cationic dyes was higher than that for anionic dyes. The adsorption kinetics was tested for the pseudo-first order and pseudo-second order kinetic models at different experimental conditions. (C) 2012 Elsevier B.V. All rights reserved.
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