Journal
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume 98, Issue -, Pages 457-459Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2012.08.078
Keywords
Ultramarine; High-pressure; Raman Spectroscopy
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Funding
- Natural Sciences and Engineering Research Council of Canada [228253]
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The resonance Raman spectrum of ultramarine has been studied as a function of pressure up to 5 GPa. The overtone progressions of the nu(1) fundamental and the combination bands of S-3(-) and the nu(1) band of S-2(-) were measured and the pressure dependences were determined. The symmetric stretching mode of S-3(-) is nearly harmonic. No phase transition was observed over the measured pressure range. (C) 2012 Elsevier B.V. All rights reserved.
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