Journal
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume 75, Issue 3, Pages 1168-1170Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2009.12.086
Keywords
Manganese; Oxygen evolving complex; ESI(+)-MS/MS; tptz
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Funding
- Research Council of Sharif University of Technology
- National Elite Foundation
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The mononuclear complex [Mn(tptz)(CH3COO)(OH2)(2)]NO3 (1) was investigated by electrospray ionization mass spectrometry in aqueous solution at pH 4.5. Electrospray ionization mass spectrometry shows that mononuclear and dinuclear manganese cationic species are present in solution, probably in equilibrium with neutral 1. An experiment showed that the most important reaction in the presence of oxone (2KHSO(5)center dot KHSO4 center dot K2SO4) is decoordination. (C) 2010 Elsevier B.V. All rights reserved.
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