Journal
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume 71, Issue 4, Pages 1594-1598Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2008.06.010
Keywords
1,4,7-Trimethyl-1,4,7-triazacyclononane; Iodine; TCNE; TCNQ; Solid CT-complexes; Infrared; Thermal; Structure
Categories
Ask authors/readers for more resources
The solid charge-transfer complexes formed in the reaction of the electron donor 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) with the acceptors iodine, tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been isolated. These were characterized through electronic and infrared spectra as well as thermal and elemental analysis. The results show that the formed solid CT-complexes have the formulas [(TMTACN)I]I(3), [(TMTACN)(TCNE)(5)] and [(TMTACN)(TCNQ)(3)] in full agreement with the known reaction stoichiometries in solution. The chloranil Cr-solid complex cannot be isolated in pure form. (C) 2008 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available