Journal
SOLID STATE IONICS
Volume 193, Issue 1, Pages 39-42Publisher
ELSEVIER
DOI: 10.1016/j.ssi.2011.03.005
Keywords
Polymer electrolytes; Lithium hexafluorophosphate; Conductivity; Thermal stability; Poly(trimethylene carbonate)
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Funding
- Fundacao para a Ciencia e Tecnologia [POCI/QUI/59856/2004, POCTI/SFA/3/686, SFRH/BD/22707/2005, SFRH/BD/38616/2007]
- University of Minho
- Fundação para a Ciência e a Tecnologia [SFRH/BD/22707/2005, PD/BD/128319/2017, POCI/QUI/59856/2004] Funding Source: FCT
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In this study the results of our characterization of a solid polymer electrolyte based on poly(trimethylene carbonate), henceforth designated as p(TMC), and lithium hexafluorophosphate (LiPF6) are described. Samples of solvent-free electrolytes were prepared with a range of concentration of guest salt using solvent casting from tetrahydrofuran and characterized by conductivity measurements, thermal analysis and electrochemical stability. Electrolytes based on this host polymer, with LiPF6, were obtained as mechanically robust, flexible, transparent and completely amorphous films. (C) 2011 Elsevier B.V. All rights reserved.
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