Journal
SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume 105, Issue -, Pages 293-301Publisher
ELSEVIER
DOI: 10.1016/j.solmat.2012.06.033
Keywords
CuCrxMn2-xO4; Sol-gel self-combustion; TSSS paint coatings; Optimization design; Spectral selectivity; Durability
Funding
- Western Light Talents Training Program of CAS
- Solar Action Plan of CAS [1731012394]
- National Natural Science Foundation of China [51003111]
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CuCrxMn2-xO4 (x = 0.5, 1) spinels, novel pigments for spectrally selective paints, have been prepared through a sol-gel combustion synthesis process. Thickness Sensitive Spectrally Selective (TSSS) paint coatings, using CuCrxMn2-xO4 (x = 0.5, 1) obtained at varied calcined temperatures (500 similar to 1100 degrees C) as pigment, were deposited on top of aluminum substrates by an cost-effective spray coating method and characterized by reflectance measurements over the spectral range of 0.3-20 mu m. Influence of pigment species and coating thickness on optical properties of paint coatings was investigated. Results suggest that CuCr0.5Mn1.5O4-based coatings are more favorable than CuCrMnO4-based ones and coatings using 700 degrees C calcined CuCr0.5Mn1.5O4 as pigment exhibit the optimum spectral selectivity (alpha(s) = 0.92 similar to 0.93, epsilon(T) = 0.22 similar to 0.31). Difference in powder thermal emittances reveals that suitable pigments can be pre-chosen before fabricating paint coatings to obtain optimum spectral selectivity. Long-term stability tests of the TSSS paint coatings were performed according to the methodology worked out within IEA-SHC Task X and the results confirmed that coatings in this study could be safely used during collector's lifetime without degradation in performance. (c) 2012 Elsevier B.V. All rights reserved.
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