Journal
SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume 95, Issue 9, Pages 2677-2684Publisher
ELSEVIER
DOI: 10.1016/j.solmat.2011.05.041
Keywords
Smart window; Vanadium dioxide; Antireflection; Optical optimization; Thin film; Solution process
Funding
- CAS [4912009YC006]
- National Key Basic Research Project (NKBRP) [2009CB939904]
- National Natural Science Foundation of China (NSFC) [50772126]
- Shanghai Key Basic Research Project [09DJ1400200]
- Shanghai Pujiang Talent Program [09PJ1410700]
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An all-solution process was developed to prepare VO2-based double-layered films containing SiO2 and TiO2 antireflection layers. These double-layered films were optimized to improve luminous transmittance (T-lum) and switching efficiency (Delta T-sol). The substrate/VO2/TiO2 double-layered structure showed the largest improvement of 21.2% in T-lum (from 40.3% to 61.5%). T-lum, could be further improved to the maximum of 84.8% by combining film thickness optimization and antireflection layer deposition. Delta T-sol, (usually below 10% for single VO2 films) could be improved by adjusting the position of antireflection peaks (the highest Delta T-sol, was 15.1%). A sample with balanced T-lum and Delta T-sol showed T-lum of about 58% (20 degrees C) and 54% (90 degrees C), and Delta T-sol of 10.9%. This work is an important technical breakthrough toward the practical application of VO2-based smart windows. (C) 2011 Elsevier B.V. All rights reserved.
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