Journal
SOLAR ENERGY
Volume 85, Issue 11, Pages 2819-2825Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.solener.2011.08.016
Keywords
Zinc oxide; Solar cell; MEH-PPV; Modification; LiTFSI; Photovoltaics
Categories
Funding
- Chinese Academy of Sciences
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
- National 973 project [2007CB936602]
- Hefei Institute of Physical Sciences
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The paper reports the improved performance by addition of lithium bis(trifluoromethanesulfonyl)amide (LiTFSI) to poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (MEH-PPV) in the hybrid solar cells consisting of MEH-PPV as an electron donor and vertically aligned ZnO nanorod array as an electron acceptor. Results show that, with increasing the weight ratio R of LiTFSI/MEH-PPV, the charge transfer efficiency at MEH-PPV/ZnO interface, the device short circuit current (J(sc)) and open circuit voltage (V-oc) get increased for R <= 2/10, but decreased when R > 2/10, resulting in a peak power conversion efficiency of eta = 0.48% for R = 2/10 at AM 1.5 illumination (100 mW/cm(2)). It is revealed that the increased J(sc) is due to the improved charge transfer between the MEH-PPV and ZnO as a result of the interaction between LiTFSI and MEH-PPV, while the increased V-oc and the decreased charge recombination are attributed to the increased hole mobility of MEH-PPV; moreover, the decreased J(sc), and V-oc at high R values are attributed to the morphology degradation in the active layer due to the high LiTFSI content. (C) 2011 Elsevier Ltd. All rights reserved.
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