Journal
SOFT MATTER
Volume 8, Issue 31, Pages 8088-8093Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sm25393c
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Funding
- National Science Foundation (NSF) [CMMI-0900468]
- NSF/MRSEC [DMR05-20020]
- NSF/NSEC [DMR08-32802]
- Div Of Civil, Mechanical, & Manufact Inn
- Directorate For Engineering [0900468] Funding Source: National Science Foundation
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We report capillary force induced instability from drying water swollen poly(2-hydroxyethyl methacrylate) (PHEMA) based hydrogel membranes with micron-sized holes in a square array. When the PHEMA membrane was exposed to deionized-water, the size of the holes became smaller but retained the shape, so-called breathing mode instability. However, during the drying process, the square pore array buckled into a diamond plate pattern. The deformed pattern could be recovered upon re-exposure to water. The instability mechanism was confirmed by comparing the observations from optical and scanning electron microscopy (SEM) images with theoretical prediction. When thermoresponsive poly(N-isopropylacrylamide) was introduced to the PHEMA gel, the poly(2-hydroxyethyl methacrylate-co-N-isopropylacrylamide) (PHEMA-co-PNIPAAm) membrane underwent pattern transformation only if dried below the lower critical solution temperature of PNIPAAm. Along the pattern transformation, we observed a dramatic change of the optical property of the film, from colourful reflection to transparent window.
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