Journal
SOFT MATTER
Volume 7, Issue 18, Pages 8030-8034Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1sm05797a
Keywords
-
Categories
Funding
- KAKENHI [20350110]
- Grants-in-Aid for Scientific Research [20350110] Funding Source: KAKEN
Ask authors/readers for more resources
We introduced different spirobenzopyran derivatives into poly(N-isopropylacrylamide) gels and evaluated the effects of spontaneous ring-opening rates of the spirobenzopyrans on light-responsive volume change behaviors of the gels. Rates of reswelling from the light-induced shrunken state of the spirobenzopyran-functionalized poly(N-isopropylacrylamide) (p(Sp-NIPAAm)) gels increased with increasing ring-opening rates of spirobenzopyrans in the gels. Bending motion of a rod-like p(Sp-NIPAAm) gel was invoked by local light-irradiation because of asymmetric shrinkage of the gel. Two types of bending motions were observed depending on the reswelling rates of the gels; a gel with a fast reswelling rate was steadily bent only during light-irradiation, whereas another gel with a slow reswelling rate showed a continuous bending motion even after the irradiation. In addition, a sheet-like gel with a fast reswelling rate was operated as a micro-conveyor whose conveying direction was arbitrarily controlled with a light-irradiation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available