Journal
ACS MACRO LETTERS
Volume 4, Issue 6, Pages 616-619Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.5b00231
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Funding
- Agency for Innovation by Science and Technology in Flanders (IWT)
- Belgian State, the Prime Minister's office [P7/05]
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A practical synthesis of unique, precisely decorated, multisegmented block copolymers was elaborated via amine-thiol-ene conjugation. By mixing the thiolactone-acrylate heterotelechelic precursor polymer with selected amines, a library of multisegmented species was obtained, featuring a high level of control over backbone structure and spatial arrangement of side chain residues. Ranging from glycosylated to amphiphilic materials, these macromolecular lineups have been analyzed by LCxSEC DOSY-NMR, and DLS, revealing the particular properties of these macromolecular structures.
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