4.7 Article

Water-in-Water Emulsions Stabilized by Nanoplates

Journal

ACS MACRO LETTERS
Volume 4, Issue 9, Pages 965-968

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.5b00480

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Funding

  1. Netherlands Organisation for Scientific Research (NWO)
  2. Marie Curie Initial Training Network Soft Matter at Aqueous Interfaces (SOMATAI)
  3. Dutch Ministry of Education, Culture, and Science (OCW)
  4. NWO Vici Grant

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Ultrathin plate-like colloidal particles are effective candidates for Pickering stabilization of water-in-water emulsions, a stabilization that is complicated by the thickness and ultralow tension of the water-water interface. Plate-like particles have the advantage of blocking much of the interface while simultaneously having a low mass. Additionally, the amount of blocked interface is practically independent of the equilibrium contact angle theta at which the water-water interface contacts the nanoplates. As a result, the adsorption of nanoplates is stronger than for spheres with the same maximal cross section, except if theta = 90 degrees.

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