Journal
SMALL
Volume 9, Issue 11, Pages 1974-1981Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201202919
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Funding
- Singapore National Research Foundation under CREATE programme: Nanomaterials for Energy and Water Management
- NTU in Singapore [M4080865.070.706022]
- NTU-SUG [M4080513]
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Single- and few-layer transition-metal dichalcogenide nanosheets, such as WSe2, TaS2, and TaSe2, are prepared by mechanical exfoliation. A Raman microscope is employed to characterize the single-layer (1L) to quinary-layer (5L) WSe2 nanosheets and WSe2 single crystals with a laser excitation power ranging from 20 W to 5.1 mW. Typical first-order together with some second-order and combinational Raman modes are observed. A new peak at around 308 cm-1 is observed in WSe2 except for the 1L WSe2, which might arise from interlayer interactions. Red shifting of the A1g mode and the Raman peak around 308 cm-1 is observed from 1L to 5L WSe2. Interestingly, hexagonal- and monoclinic-structured WO3 thin films are obtained during the local oxidation of thinner (1L-3L) and thicker (4L and 5L) WSe2 nanosheets, while laser-burned holes are found during the local oxidation of the WSe2 single crystal. In addition, the characterization of TaS2 and TaSe2 thin layers is also conducted.
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