4.4 Article

Absorption of NO by Aqueous Solutions of KMnO4/H2SO4

Journal

SEPARATION SCIENCE AND TECHNOLOGY
Volume 49, Issue 13, Pages 2085-2089

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/01496395.2014.907809

Keywords

absorption; reaction kinetics; nitric oxide; stirred tank reactor; KMnO4/H2SO4

Funding

  1. Natural Science Foundation of Shanghai [14ZR1417800]
  2. Science and Technology Commission of Shanghai Municipality [11dz2281700, 13dz1202703, 14DZ1200201, 14DZ1200202]
  3. Shanghai Municipal Education Commission [11YZ196]

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The absorption of NO in aqueous solutions of KMnO4 and H2SO4 was carried out in a stirred tank reactor under atmosphere pressure. The results indicated that the absorption process was under a fast pseudo-m th reaction regime. The reaction between NO and aqueous solutions of KMnO4/H2SO4 was found to be first-order with respect both to NO and to KMnO4. The addition of H2SO4 to KMnO4 solutions increased the absorption rate of NO and increasing reaction temperature was also favorable to the absorption of NO.

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