Journal
SEPARATION SCIENCE AND TECHNOLOGY
Volume 45, Issue 16, Pages 2431-2436Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/01496395.2010.510094
Keywords
actinide; extraction; lanthanide; separation
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The extractability and complexation properties of lanthanides with N-alkyl-N-phenyl-1,10-phenanthroline-2-carboxamide were investigated. These ligands, which contain two aza-aromatic donors and an oxygen donor in a molecule, are newly developed extractants for actinides and lanthanides. N-Octyl-N-tolyl-1,10-phenanthroline-2-carboxamide exhibited high extractability of Eu3+ even under acidic conditions. In addition, strong complexation in acidic media was confirmed by spectroscopic titration experiments. Investigation of the complexation equilibrium revealed that the presence of an oxygen donor promotes ligand coordination with lanthanides over the competing protonation reaction in acidic solution.
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