Journal
SEPARATION SCIENCE AND TECHNOLOGY
Volume 44, Issue 5, Pages 1045-1073Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/01496390902729130
Keywords
Adsorption kinetic; adsorption equilibrium; carbon dioxide; hydrogen; pressure swing adsorption
Funding
- European Project HY2SEPS (Hybrid Hydrogen - Carbon Dioxide Separation Systems) [019887]
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The design of a layered pressure swing adsorption unit to treat a specified off-gas stream is based on the properties of the adsorbent materials. In this work we provide adsorption equilibrium and kinetics of the pure gases in a SMR off-gas: H2O, CO2, CH4, CO, N2, and H2 on two different adsorbents: activated carbon and zeolite. Data were measured gravimetrically at 303-343K and 0-7bar. Water adsorption was only measured in the activated carbon at 303K and kinetics was evaluated by measuring a breakthrough curve with high relative humidity.
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