Towards conductive-gel-free electrodes: Understanding the wet electrode, semi-dry electrode and dry electrode-skin interface impedance using electrochemical impedance spectroscopy fitting

The electrode-scalp impedance of six subjects is studied by electrochemical impedance spectroscopy using three representative electrodes, namely wet electrodes, semi-dry electrodes, and dry electrodes. With the analysis of proposed equivalent models and area-normalized impedance (kQ cm(2)), the specific electrode double layer resistances are 530 Q cm(2) for all electrodes, their specific contact resistances R are 80 Q cm(2), 114 Q cm(2) and 20,077 Q cm(2), and their specific skin resistances 13., are 867 Q cm(2), 1730 Q cm(2) and 46,145 Q cm(2) for these three representative electrodes respectively. When pressure was applied on dry electrodes, R reduced by 47% and Rs reduced by 81%. When pressure was applied on semi-dry electrodes, Rs reduced by 50% (R is not applicable for semi-dry electrodes). After application of scalp abrasion for dry electrodes, R reduced by 36% and Rs reduced by 82%. After application of scalp abrasion for semi-dry electrodes, Rs reduced by 64%. Seeking novel interface materials may break through the bottleneck for dry electrodes development in terms of integrated materials, mechanical support and electronic circuitry, while semi-dry electrodes have much development space to meet a balance of quick setup, comfortable wear, and satisfactory signal quality in many medical and out-clinic applications.