Journal
SENSORS AND ACTUATORS B-CHEMICAL
Volume 181, Issue -, Pages 749-755Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2013.01.090
Keywords
Coumarin Schiff base; Fluorescence turn-on; Chemosensor; Detection; Photoisomer
Funding
- National Natural Science Foundation of China [20904010, 21274045]
- Pearl River in Guangzhou city of Nova of Science and Technology Special Funded Projects [2012J2200009]
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A novel coumarin Schiff base compound (L) prepared from 4-(diethylamino)salicylaldehyde and 6-amino-7-hydroxycoumarin was synthesized and evaluated as a chemoselective Fe3+ and Al3+ sensor utilizing turn-on fluorescence enhancement. There were 7-fold and 4-fold fluorescence enhancement of L at lambda(em,max) = 488 nm upon the addition of 1 equiv. of Al3+ and Fe3+, respectively. Other metal ions, such as K+, Li+, Na+, Cu+, Mg2+, Ca2+, Ba2+, Cu2+, Fe2+, Hg2+, Ni2+, Sb3+, Sn2+, Zn2+, Ce3+, Cr3+, Pr3+, Sm3+ and Sn4+ had no such significant effect on the fluorescence of L, whereas In3+ and Ga3+ induced slightly fluorescence enhancement of L. In addition, rapid photoresponse through fluorescence turn-on signaling displayed L via intramolecular O-H center dot center dot center dot N=CH interaction in photoisomerized product (L') has been described, where showed 130-fold and 65-fold fluorescence enhancement at lambda(em,max) = 488 and 516 nm, respectively. The results indicated L' was less reactive or inert toward metal ions. (c) 2013 Elsevier B.V. All rights reserved.
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