Journal
SENSORS AND ACTUATORS B-CHEMICAL
Volume 185, Issue -, Pages 188-194Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2013.04.109
Keywords
Copper(II) recognition; Sulfide recognition; Fluorescence; Benzimidazole; Copper displacement
Funding
- NSFC [21176029]
- Natural Science Foundation of Liaoning Province [20102004]
- Program for Liaoning Excellent Talents in University [LJQ2012096]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
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To realize highly selective relay recognition of Cu2+ and sulfide ions, a simple benzimidazole-based fluorescent chemosensor (1) was designed and synthesized. Sensor 1 displays rapid, highly selective and sensitive recognition to Cu2+ in 100% water solution at pH 6.0. The in situ generated 1-Cu2+ complex solution exhibit a fast response and high selectivity toward sulfide anion via Cu2+ displacement approach. The detection limits of sensor 1 to Cu2+ and 1-Cu2+ complex to sulfide anion were estimated to be 3.5 x 10(-7) M and 1.35 x 10(-6) M, respectively. Proof-of-concept experiment results demonstrate that sensor 1 has potential utilities for Cu2+ and sulfide ion concentration evaluation in real water samples. This successive recognition feature of sensor 1 makes it has a potential utility for Cu2+ and sulfide anion detection in water. (C) 2013 Elsevier B.V. All rights reserved.
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